波形驱动下多参数约束高分辨率反演方法——以四川盆地渝西地区龙马溪组页岩气为例

基于叠后地震波形指示反演在薄储层预测方面的优势，以及叠前弹性参数较叠后弹性参数信息更丰富、对储层的敏感性更高的特点，根据岩石物理资料，应用地震驱动+储层构型约束的高精度叠前随机反演方法，探寻定量表征优质薄页岩的技术，以期为深层页岩气地质甜点预测提供技术支撑。首先，基于道集波形相似性、AVO特征和空间距离的三变量优选方法提取结构相似的井数据作为空间估值样本，然后建立待判别道集初始模型；其次，以统计的弹性阻抗作为先验信息，应用“基于叠前道集特征指示的马尔科夫链-蒙特卡洛随机模拟算法”进行叠前地震波形指示反演，最终得到高精度的叠前弹性参数反演成果。实际应用表明，应用所提方法有效预测了龙一段一亚段1-2小层优质页岩厚度，基于特征参数的井震高频模拟精确模拟了龙一段一亚段1-2小层地质甜点参数，为页岩气勘探提供了技术支撑。     

Nonlinear control of the dissolved oxygen concentration integrated with a biomass estimator for production of Bacillus thuringiensis δ-endotoxins

Bacillus thuringiensis is a microorganism that allows the biosynthesis of δ-endotoxins with toxic properties against some insect larvae, being often used for the production of biological insecticides. A key issue for the bioprocess design consists in adequately tracking a pre-specified optimal profile of the dissolved oxygen concentration. To this effect, this paper aims at developing a novel control law based on a nonlinear dynamic inversion method. The closed-loop strategy includes an observer based on a Bayesian Regression with Gaussian Process, which is used for on-line estimating the biomass present in the bioreactor. Unlike other approaches, the proposed controller leads to an improved response time with effective disturbance rejection properties, while simultaneously prevents undesired oscillations of the dissolved oxygen concentration. Simulation results based on available experimental data were used to show the effectiveness of the proposal.     

A Gauss–Newton full-waveform inversion for material profile reconstruction in viscoelastic semi-infinite solid media

An inversion framework employing a Gauss–Newton method is developed to reconstruct material profiles in heterogeneous, viscoelastic, semi-infinite domains. In particular, a full-waveform inversion approach is investigated to image the elastic and attenuating parameters of a layered media. To account for the viscoelasticity of the medium, a Generalized Maxwell Body with one spring and two Maxwell elements in parallel (GMB2) is adopted in the forward and inverse wave propagation problems. Perfectly-matched-layers were introduced as wave absorbing buffers to simulate the semi-infinite extent of the domain. Using transient wave equations endowed with the GMB2 constitutive relation and the PML, a partial-differential-equations-constrained optimization scheme was implemented that lead to classic KKT (Karush–Kuhn–Tucker) conditions including time-dependent state, adjoint, and time-invariant control problems. An optimal solution of the viscoelastic parameters was obtained using a reduced-space approach based on a line search algorithm where the search direction was computed by the Gauss–Newton method. Considerable improvements on the accuracy and convergence rate of solutions were made by the developed Gauss–Newton inversion procedure compared to previous research using the Fletcher–Reeves method.     

基于狼群算法的概率积分法模型参数反演方法研究

概率积分法模型属于典型的多元复杂非线性函数,且部分参数存在相关性,使得概率积分法模型参数反演一直是开采沉陷数据处理的热点问题和难点问题。WPA(狼群算法)作为一种新群体智能算法,已在多维背包求解问题、水电站水库优化调度以及旅行商等复杂非线性最优化问题中得到成功应用,但在开采沉陷数据处理领域尚未见文献报道。鉴于此,本文首次将WPA引入概率积分法模型参数反演中,构建了基于WPA的概率积分法模型参数反演方法。研究结果表明:WPA反演概率积分法模型参数具有较高的准确度、较好的精度、良好的稳健性,且满足工程应用标准。本文研究成果对概率积分法模型参数精准反演具有重要参考价值。     

Porous Perovskite Fibers – Preparation by Wet Phase Inversion Spinning and Catalytic Activity

Porous perovskite (LaMnO₃) fibers were prepared by means of wet phase inversion spinning. The influence of different spinning procedures, slurry and coagulation bath composition on fiber shape and pore morphology was studied. The catalytic activity of the prepared fibers was tested for carbon monoxide oxidation as a model reaction in a differential recycle reactor. The results revealed that by suitable choice of process conditions porous catalytically active fibers can be prepared. Catalytic measurements confirmed that the catalytic fibers exhibit an open structure that allows full utilization of the catalytically active surface without intraparticle diffusional limitations.     

海相页岩TOC地震定量预测技术及其应用——以四川盆地焦石坝地区为例

总有机碳含量(TOC)是评价页岩生烃能力和页岩油气藏的一个重要指标,目前国内外利用地震资料直接定量预测TOC的报道很少,因此,有必要对地震预测TOC的方法作进一步的研究。为此,以四川盆地焦石坝地区为例,从岩心实测TOC出发,通过TOC与地球物理参数交会分析,寻找到TOC敏感地球物理参数——密度,并建立密度与TOC之间的最佳拟合方程,得到计算总有机碳含量的经验公式;结合叠前地震反演获得的密度体便可计算出TOC数据体,从而达到定量预测页岩TOC的目的。将改进的预测方法应用于四川盆地焦石坝地区海相页岩气勘探,结果表明:①利用叠前同时反演直接求得的密度体避免了累计误差,稳定性好,多解性少,结果可靠,为精细定量预测TOC提供了基础保证;②预测的TOC与实测结果吻合程度高,相对误差较小。结论认为,该技术在四川盆地海相页岩气勘探中具有广阔的应用前景。     

Effect of anode structure on performance of cone-shaped solid oxide fuel cells fabricated by phase inversion

Anode-supported cone-shaped tubular solid oxide fuel cells (SOFCs) are successfully fabricated by a phase inversion method. During processing, the two opposite sides of each cone-shaped anode tube are in different conditions--one side is in contact with coagulant (the corresponding surface is named as “W-surface”), while the other is isolated from coagulate (I-surface). Single SOFCs are made with YSZ electrolyte membrane coated on either W-surface or I-surface. Compared to the cell with YSZ membrane on W-surface, the cell on I-surface exhibits better performance, giving a maximum power density of 350 mW cm⁻² at 800 °C, using wet hydrogen as fuel and ambient air as oxidant. AC impedance test results are consistent with the performance. The sectional and surface structures of the SOFCs were examined by SEM and the relationship between SOFC performance and anode structure is analyzed. Structure of anodes fabricated at different phase inversion temperature is also investigated.     

Effect of Isomeric Propanols on the Performances of Polyethersulfone Nanofiltration Membranes

Abstract

In this work, polyethersulfone (PES) asymmetric nanofiltration (NF) membranes were prepared by immersion precipitation phase inversion process. The casting solution contained N-methyl-2-pyrrolidone (NMP) as solvent, 1-propanol and 2-propanol as nonsolvent additives, and polyvinylpyrrolidone (PVP) as pore former additive. Water was used as a coagulant. The effects of the PVP content in the casting solution and the exposed time on the performances of the NF membranes were investigated. It was found that with the increase of PVP content, the pure water flux (PWF) increased to the largest value and then decreased. The rejection to PEG 1000 always decreased. The largest value (1281.40 kg · m^?2 · h^?1 · MPa^?1) of PWF appeared when the content of 1-propanol was 9 wt.%. However, when 2-propanol was added in the casting solution, the largest value of PWF was only 678.37 kg · m^?2 · h^?1 · MPa^?1 (the content of 2-propanol was 7 wt.% and other preparing conditions were unchanged). The results meant that both PWF and rejection of the membranes with 1-propanol as additive were higher than that of 2-propanol as additive. The possible reason was discussed from the viewpoint of the difference of solubility of propanols to PES and PVP.     

Analytic inversion for a general case of certain classes of matrices

The explicit inverse and determinant of a class of matrices are presented. The class under consideration is defined by 4n ? 2 parameters, analytic expressions of which form the elements of the upper Hessenberg type inverse. These analytic expressions enable recursion formulae to be obtained, which reduce the arithmetic operations to O(n ²). The Hadamard product of two specific structures' matrices provides the class presented, special cases of which are already known classes of test matrices.